|
KMID : 1059519890330050477
|
|
Journal of the Korean Chemical Society
1989 Volume.33 No. 5 p.477 ~ p.483
|
|
|
Oxygen-atom Transfer of Bis(diethyldithiocarbamato)dioxomolybdenum (VI) with Triphenylphosphine in 1,2-Dichloroethane
|
|
Kim Chang-Su
Song Se-June
Oh Chang-Eon
|
|
|
Abstract
|
|
|
|
The rates of the reaction of [MoO2(S2CNEt2)2] with triphenylphosphine in 1,2-dichloroethane have been determined by the spectrophotometric method. The increase in the initial absorbance has been interpreted as a result of the production of [Mo2O3(S2CNEt2)4] and the decrease in absorbance then corresponds to the reduction of [M2O3(S2CNEt2)4]. The data suggest mechanisms involving the enzymatic reaction in the first stage and the decay of intermediate, μ-oxo molybdenum (Ⅴ) dimer in the second stage.
|
|
|
KEYWORD
|
|
|
|
|
|
FullTexts / Linksout information
|
|
|
|
|
|
Listed journal information
|
|
|